Crystal structure of (RS)-(4-chloro­phen­yl)(pyridin-2-yl)methanol

Narayana, B. and Sarojini, B. K. and Yathirajan, H. S. and Rathore, Ravindranath and Glidewell, Christopher (2016) Crystal structure of (RS)-(4-chloro­phen­yl)(pyridin-2-yl)methanol. Acta Crystallographica Section E, 72 (1). pp. 69-72. ISSN 2056-9890

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Abstract

In the title racemic compound, C12H10ClNO, the dihedral angle between the benzene and pyridine rings is 74.34 (6)°. In the crystal, the mol­ecules are linked by O—H⋯N hydrogen bonds, forming zigzag C(5) [001] chains in which alternating R- and S-configuration mol­ecules are related by c-glide symmetry. In addition, inversion-related pairs of mol­ecules are linked into dimers by pairs of weak C—Cl⋯π(pyrid­yl) inter­actions, which link the hydrogen-bonded chains into (100) sheets. Structural comparisons are drawn with a number of related compounds.

Item Type:	Article
Uncontrolled Keywords:	crystal structure, supramolecular structure, hydrogen bonds, halogen-pyridine interactions
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	C Swapna Library Assistant
Date Deposited:	13 Nov 2019 05:37
Last Modified:	13 Nov 2019 05:37
URI:	http://eprints.uni-mysore.ac.in/id/eprint/9996

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