Crystal and molecular structure studies of tris (2-hydroxy-3-t-butyl-5-methylbenzene)-methane trihydrate and N-benzyl-N-phenyl benzamide

Rangappa, K. S. and Mallesha, H. and Anil Kumar, N. V. and Yathirajan, H. S. and Sridhar, M. A. and Lokanath, N. K. and Shashidhara Prasad, J. (2000) Crystal and molecular structure studies of tris (2-hydroxy-3-t-butyl-5-methylbenzene)-methane trihydrate and N-benzyl-N-phenyl benzamide. Journal of Chemical Crystallography, 30 (4). pp. 255-258. ISSN 1074-1542

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Abstract

The structures of the title compounds, tris(2-hydroxy-3-t-butyl-5-methylbenzene)- methane (C34H46O3. 3H(2)O, 3) and N-benzyl-N-phenylbenzamide (C20H17NO, 6), have been investigated by X-ray crystallography. Compound 3 crystallizes in the trigonal space group P(3) over bar with cell parameters a = 14.090(5) Angstrom, b = 14.090(5)Angstrom, c = 10.485(5)Angstrom, Z = 2. Compound 6 crystallizes in the monoclinic space group C2/c with cell parameters a = 24.533(4)Angstrom, b = 9.176(4)Angstrom, c = 16.711(5)Angstrom, beta = 125.88(2)degrees Z = 8. Compound 3 has both intra-and intermolecular hydrogen bonds. It also exhibits a helical columnar arrangement of the molecules and goes into mesophase before melting into an isotropic liquid.

Item Type:	Article
Uncontrolled Keywords:	THBMBM; BPB; crystal structure; helical packing; columnar packing; mesophase transition
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 19 not found.
Date Deposited:	25 Sep 2019 06:00
Last Modified:	01 Dec 2022 06:11
URI:	http://eprints.uni-mysore.ac.in/id/eprint/8501

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