Synthesis and crystal structure of 1-(Cyano(4-methoxyphenyl)methyl)cyclohexyl acetate

Mantelingu, K. and Kavitha, C. V. and Rangappa, K. S. and Naveen, S. and Sridhar, M. A. and Shashidhara Prasad, J. (2007) Synthesis and crystal structure of 1-(Cyano(4-methoxyphenyl)methyl)cyclohexyl acetate. Molecular Crystals and Liquid Crystals, 469 (1). pp. 121-129. ISSN 1563-5287

Text (Full Text) Synthesis and Crystal Structure of 1-(Cyano(4-methoxyphenyl)methyl)cyclohexyl Acetate.pdf - Published Version Restricted to Registered users only Download (647kB) | Request a copy

Abstract

The title compound, C17H21NO3, was synthesized by the acetylation of the hydroxy group of 1-(cyano(4-methoxyphenyl)methyl)cyclohexanol, which was formed by the reaction of 4-methoxyphenyl acetonitrile with cyclohexanone. The compound was characterized spectroscopically, and the structure was investigated by X-ray crystallography. The compound crystallizes in the orthorhombic crystal class in the space group Pbca with cell parameters a = 13.412(6) Å, b = 12.398(14) Å, c = 19.026(19) Å and V = 3164(5) Å 3 for Z = 8. The cyclohexane ring is in a chair conformation. The structure exhibits intermolecular hydrogen bonds of the type C–H…N and C–H…O.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	C Swapna Library Assistant
Date Deposited:	24 Sep 2019 05:52
Last Modified:	24 Sep 2019 05:52
URI:	http://eprints.uni-mysore.ac.in/id/eprint/8429

Actions (login required)

View Item