(3-Chloro­prop­yl)tri­phenyl­phospho­nium bromide

Kavitha, C. N. and Yathirajan, H. S. and Dayananda, A. S. and Gerber, Thomas and Hosten, Eric and Betz, Richard (2012) (3-Chloro­prop­yl)tri­phenyl­phospho­nium bromide. Acta Crystallographica Section E, 68 (11). o3115. ISSN 2056-9890

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Abstract

The title compound, C21H21ClP+Br−, is the bromide salt of a mixed aryl-alkyl phospho­nium cation. C–P–C angles span a range of 107.20 (10)–111.18 (10)°. The non-H atoms of the 3-chloro­propyl group adopt a staggered conformation [C–C–C–Cl torsion angle: −72.0 (3)°]. In the crystal, C—H⋯Br contacts connect the entities of the title compound into a double zigzag chain along b. These chains are linked into a supra­molecular layer lying parallel to (10-1) by C—H⋯π inter­actions.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	C Swapna Library Assistant
Date Deposited:	27 Aug 2019 10:01
Last Modified:	27 Aug 2019 10:01
URI:	http://eprints.uni-mysore.ac.in/id/eprint/7138

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