Cinnarizinium 3,5-di­nitro­salicylate

Dayananda, A. S. and Yathirajan, H. S. and Gerber, Thomas and Hosten, Eric and Betz, Richard (2012) Cinnarizinium 3,5-di­nitro­salicylate. Acta Crystallographica Section E, 68 (4). o1165-o1166. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S1600536812011518

Abstract

The title compound [systematic name: 4-diphenyl­methyl-1-(3-phenylprop-2-en-1-yl)-piperazin-1-ium 2-carb­oxy-4,6-dinitro­pheno­late], C26H29N2+·C7H3N2O7−, is the dinitro­salicylate salt of a tertiary amine. Deprotonation of the carb­oxy­lic acid group occurred on the phenolic hy­droxy group. The diaza­cyclo­hexane ring adopts a chair conformation. Intra­molecular O—H⋯O and inter­molecular C—H⋯O and N—H⋯O hydrogen bonds are observed. The N—H⋯O hydrogen bonds are bifurcated at the H atom and connect the cinnarizinium and 3,5-dinitro­salicylate ions together. Inter­molecular C—H⋯O hydrogen bonds connect the components into layers perpendicular to the crystallographic a axis.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 23 Aug 2019 09:28
Last Modified: 23 Aug 2019 09:28
URI: http://eprints.uni-mysore.ac.in/id/eprint/6962

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