Sunil Kumar, P. and Rai, K. M. Lokanatha (2012) Cleavage of 3-Aryl-5,6-dihydro-4H-1,2-oxazines using Zinc and Aqueous Chelating Ethers: efficient methodology for N-O Bond Cleavage. Letters in Organic Chemistry, 9 (6). pp. 440-446. ISSN 1875-6255
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Official URL: https://dx.doi.org/10.2174/157017812801322471
Abstract
A mild and efficient methodology for single pot ring opening of 3-aryl-4H-1,2-oxazines to gamma-hydroxy ketones was developed using zinc and aqueous chelating ethers. The ether acts as ligand and co-solvent for the reaction. The ability of zinc ions to form stable complexes with chelating ethers activates the zinc towards reduction. Water is the proton source.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | C Swapna Library Assistant |
| Date Deposited: | 18 Jul 2019 10:17 |
| Last Modified: | 13 Jan 2023 11:20 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/5353 |
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