4-Iodo-N-(o-tolyl­sulfon­yl)benzamide

Naveen, S. and Suresha, E. and Sudha, A. G. and Lokanath, N. K. and Suchetan, P. A. and Abdoh, M. (2017) 4-Iodo-N-(o-tolyl­sulfon­yl)benzamide. IUCrData, 2 (1). x162030. ISSN 2414-3146

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Abstract

The title compound, C\sb 14H\sb 12INO\sb 3S, crystallizes with two independent mol\-ecules (\it A and \it B) in the asymmetric unit. The dihedral angle between the two aryl rings is 83.1(4)\circ in mol\-ecule \it A and 79.8(4)\circ in mol\-ecule \it B. In the crystal, the two mol\-ecules are linked by a pair of N—-H⋅sO hydrogen bonds, forming an \it A—\it B dimer with an \it R\sb 2\sp 2(8) ring motif. The dimer is further strengthened by a pair of C—-H⋅sO hydrogen bonds with an \it R\sb 2\sp 2(14) motif. Another pair of C—-H⋅sO inter\-actions assembles these dimers along the diagonal of the \it bc plane, forming ribbons. Adjacent ribbons are connected by C—-H⋅sπ\sb ar\-yl inter\-actions between the \it A mol\-ecules, and thus the overall supra\-molecular architecture is one-dimensional.

Item Type:	Article
Uncontrolled Keywords:	crystal structure, sulfonamides, benzamide, o-tolylsulfony, hydrogen bonding, C-H...pi interactions
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Institution of Excellence
Depositing User:	C Swapna Library Assistant
Date Deposited:	17 Jun 2019 09:50
Last Modified:	21 Jun 2022 09:49
URI:	http://eprints.uni-mysore.ac.in/id/eprint/3279

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