Opipramolium fumarate

Siddegowda, M. S. and Jasinski, J. P. and Golen, James A. and Yathirajan, H. S. and Swamy, M. T. (2011) Opipramolium fumarate. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67 (9). O2296-U2294. ISSN 1600-5368

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Abstract

In the crystal structure of the title salt {systematic name: 4-3-(5H-dibenzb,f]azepin-5-yl)propyl]-1-(2-hydroxyethyl)-piperazin -1-ium (2Z)-3-carboxyprop-2-enoate}, C23H30N3O+center dot C4H3O4-, the piperazine group in the opipramol cation is protonated at only one of the N atoms. In the cation, the dihedral angle between the two benzene rings is 53.5 (6)degrees. An extensive array of intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds and weak intermolecular N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions dominate the crystal packing.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 23 not found.
Date Deposited:	08 Aug 2019 12:08
Last Modified:	25 Jul 2022 07:39
URI:	http://eprints.uni-mysore.ac.in/id/eprint/2410

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