4-Bis(4-fluorophenyl)methyl]piperazin-1-ium 2-(2-phenylethyl)benzoate

Betz, Richard and Gerber, Thomas and Hosten, Eric and Dayananda, A. S. and Yathirajan, H. S. (2011) 4-Bis(4-fluorophenyl)methyl]piperazin-1-ium 2-(2-phenylethyl)benzoate. Acta Crystallographica Section E-Structure Reports Online, 67 (10). o2783. ISSN 1600-5368

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Abstract

The asymmetric unit of the title salt, C17H19F2N2+center dot C15H13O2-, derived from a 1,4-diazacyclohexane derivative and a carboxylic acid, contains two formula units. The cation is protonated at the secondary amine functionality. The six-membered heterocycles adopt chair conformations. The fluorophenyl rings in the two cations make dihedral angles of 77.21 (19) and 78.8 (2)degrees while the aromatic rings in the anions enclose angles of 69.5 (2) and 69.9 (2)degrees. In the crystal, classical N-H center dot center dot center dot O hydrogen bonds as well as C-H center dot center dot center dot F and C-H center dot center dot center dot O contacts connect the entities into layers parallel to ac.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 23 not found.
Date Deposited:	14 Aug 2019 07:42
Last Modified:	25 Jul 2022 06:59
URI:	http://eprints.uni-mysore.ac.in/id/eprint/2390

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