Synthesis, Characterization and Antibacterial Activity of Complexes of Lanthanide(III) Nitrates with 2-Chloro-10-[3-(Diethylamino)Propyl]-Phenothiazine

Keshavan, B. and Radhika, R. T. (1999) Synthesis, Characterization and Antibacterial Activity of Complexes of Lanthanide(III) Nitrates with 2-Chloro-10-[3-(Diethylamino)Propyl]-Phenothiazine. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 29 (8). pp. 1339-1352.

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Abstract

Fourteen new complexes of lanthanide(III) nitrates with 2-chloro-10-3-diethylaminopropyl]phenothiazine (chlorproethazine) of the type Ln(CPE)(2)(NO3)(2)]NO3 (where Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and CPE = chlorproethazine) have beerl synthesised and characterized on the basis of elemental analyses, magnetic moments, molar conductance measurements, IR, electronic spectra. TG and DTA. The analytical data suggest the Ln(3+) ions are eight-coordinate. The nephelauxetic ratios (beta), bonding parameters (b(1/2)), Sinha's parameters (delta%) and covalency angular overlap parameters (eta) have been calculated for the Pr(III), Nd(III) and Er(III) complexes. The complexes: have been screened for their antibacterial activities against four bacteria.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 23 not found.
Date Deposited:	21 Jun 2021 05:53
Last Modified:	30 May 2022 11:24
URI:	http://eprints.uni-mysore.ac.in/id/eprint/16779

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