Synthesis, spectral, magnetic, thermal and antibacterial properties of metal complexes of isothipendyl.

Shanmukhappa, S. and Ramappa, P. G. (1997) Synthesis, spectral, magnetic, thermal and antibacterial properties of metal complexes of isothipendyl. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27 (7). pp. 967-983. ISSN 0094-5714

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Abstract

New complexes of Mn(II), Cr(III), UO2(VI), Zn(II) and Cd(II) with isothipendyl hydrochloride (IPH.HCl) were prepared and their structures were determined by elemental analyses, IR, H-1 NMR and reflectance spectra as well as magnetic susceptibility and conductivity measurements. The spectral data suggest the bidentate nature of IPH in the complexes. An octahedral structure is proposed for the Mn(II), Cr(III) and UO2(VI) complexes, while a tetrahedral structure is suggested for the Zn(II) and Cd(II) complexes. Thermal studies (TGA/DTA) have been used to evaluate kinetic properties such as order of thermal reaction (n) and activation energy (Ea). The results of the antibacterial activity studies show that the complexes strongly inhibit Eschearichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Klebsiella.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Users 23 not found.
Date Deposited:	27 May 2021 08:51
Last Modified:	18 Nov 2022 10:23
URI:	http://eprints.uni-mysore.ac.in/id/eprint/16658

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