Crystal structure of mesogenic material–2-(4′-cyano phenyl)-5-n-heptyl-l, 3 dioxane

Bellad, S. B. and Babu, A. M. and Sridhar, M. A. and Indira, A. and Madhava, M. S. and Shashidhara Prasad, J. (1993) Crystal structure of mesogenic material–2-(4′-cyano phenyl)-5-n-heptyl-l, 3 dioxane. Zeitschrift Fur Kristallographie, 208 (1). pp. 43-48.

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Abstract

The crystalline form of 2-(4'-cyano phenyl)-5-n heptyl-1,3 dioxane C18NO2H25 is orthorhombic and is assigned to space group P2(1)2(1)2(1) with four molecules per unit cell. The cell parameters are a = 5.5450(2) angstrom, b = 7.7334(3) angstrom, c = 41.0765(2) angstrom. D(calc) = 1.082 Mg . m-3. The structure was refined to an R = 0.07 for 840 counter intensities. The molecule is linear. The packing of the molecules shows a strong layered arrangement. This mesogenic compound exhibits a smectic phase in the range 53-55-degrees-C during heating and 55-42-degrees-C during cooling.

Item Type: Article
Subjects: D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: Users 23 not found.
Date Deposited: 04 May 2021 05:35
Last Modified: 13 Dec 2022 05:47
URI: http://eprints.uni-mysore.ac.in/id/eprint/16342

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