When hydrogen bond tailors molecular packing in non-anisometric molecules. The case study of N-alkyl 1,3-diphenyl-4,5-dihydro-1H-pyrazole-5-carboximidamides

Kotian, Sumana Y. and Shridevi, D. and Ningaiah, Srikantamurthy and Merlo, Aloir A. and Vieira, Andre A. and Bechtold, Ivan H. and Rai, K. M. Lokanatha (2020) When hydrogen bond tailors molecular packing in non-anisometric molecules. The case study of N-alkyl 1,3-diphenyl-4,5-dihydro-1H-pyrazole-5-carboximidamides. Liquid Crystal, 48 (3). pp. 395-404. ISSN 1366-5855

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Abstract

In this paper, we report the synthesis of novel liquid crystals (LCs) based on 5-membered pyrazoline heterocycle. The synthesis of pyrazoline derivative was carried out by 3 + 2] 1,3-dipolar cycloaddition reaction of benzaldehyde phenyl hydrazone (1) with acrylonitrile, mediated by chloramine-T as the oxidising agent, followed by addition of hydroxylamine hydrochloride, and subsequently alkylated with various alkyl chains to afforded the title compounds. The LCs properties were investigated using differential scanning calorimetry and polarising optical microscopy. For title compounds with longer alkyl chains, monotropic columnar hexagonal mesophase was characterised by XRD analysis. The mesophase-formation was driven by intermolecular hydrogen bonds despite their non-discoid molecular structure. GRAPHICS] .

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Mr Umendra uom
Date Deposited:	20 Feb 2021 09:40
Last Modified:	11 Feb 2022 05:58
URI:	http://eprints.uni-mysore.ac.in/id/eprint/15558

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