Kinetics and mechanism of oxidation of substituted ethanols by bromamine-t in acid-medium

Puttaswamy and Mahadevappa, D. S. (1990) Kinetics and mechanism of oxidation of substituted ethanols by bromamine-t in acid-medium. Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry, 29 (1). pp. 42-45. ISSN 0975-0975

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Abstract

The kinetics of oxidation of seven primary alcohols, RCH2CH2OH (where R = -H, -OC2H5, -OCH3, -NH2, -Cl, -Br and –NO2) by bromamine-T in the presence of HCl has been studied at 45°. The rates show first order dependence on [BAT] and fractional order each on [alcohol]0, [H+] and [Cl-]. Variations of ionic strength and dielectric constant of the medium and addition of reaction product (toluenesulphonamide) have no effect on the rate. Formation constants and decomposition constants of alcohol- BAT complexes have been determined. The rates do not correlate satisfactorily with Taft substituent constants

Item Type:	Article
Uncontrolled Keywords:	Chemistry, Multidisciplinary
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	Dr Raju C
Date Deposited:	21 Jan 2021 09:43
Last Modified:	27 Jan 2021 05:49
URI:	http://eprints.uni-mysore.ac.in/id/eprint/15429

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