Physico-mechanical, optical, and WAXS studies on chain extended polyurethane

Kendagannaswamy, B. K. and Annadurai, V. and Siddaramaiah, V. and Somashekar, R. (2000) Physico-mechanical, optical, and WAXS studies on chain extended polyurethane. Journal of Macromolecular Science-Pure and Applied Chemistry, 37 (12). pp. 1617-1625.

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Abstract

Thermoset polyurethane (PU) elastomers were prepared using castor oil, 4,4'-methylenebis(phenyl isocyanate) (MDI), and toluene-2,4-diisocyanate (TDI). The effect of aromatic diamines on the physico-mechanical and optical properties of chain extended polyurethane prepared using castor oil has been investigated. Tensile strength and percent elongation lies in the range 13-24 MPa and 76-32, respectively. Higher tensile strength was observed for 4, 4'-diaminodiphenylsulphone (DDS) than the 4,4'-diaminodiphenylmethane (DDM) chain extender. The properties imparted by the extenders are explained on the basis of the groups present in the diamines. These changes have been interpreted quantitatively in terms of microcrystalline parameters computed using wide-angle X-ray scattering data.

Item Type: Article
Uncontrolled Keywords: WAXS; polyurethane chain extenders; tensile strength; crystal size; strain
Subjects: C Chemical Science > Chemistry
D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: C Swapna Library Assistant
Date Deposited: 18 Dec 2020 10:13
Last Modified: 18 Dec 2020 10:13
URI: http://eprints.uni-mysore.ac.in/id/eprint/14237

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