Intensity measurements and relative band strengths of the fluorescent bands of the (B-X) system of I2

Sreedhara Murthy, N. and Bagare, S. P. (1980) Intensity measurements and relative band strengths of the fluorescent bands of the (B-X) system of I2. Journal of Quantitative Spectroscopy and Radiative Transfer, 24 (4). pp. 319-322. ISSN 0022-4073

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Abstract

Relative integrated intensities of a few bands in the vibrational structure of the B-X fluorescent system of molecular iodine have been measured by the technique of photographic photometry. Reliable values of Franck-Condon factors and r-centroids given recently by Tellinghuisen have been employed to evaluate the variation of electronic transition moment with internuclear separation. The variation is found to be Re(r̄) = const.(1−0.6930r + 0.1201r2) in the range 2.76 < r < 2.81 Å. Smoothed arrays of band strengths are presented for the bands. The effective vibrational temperature of the source is found to be 340 ± 55 K.

Item Type: Article
Subjects: D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: Dhruva Kumar
Date Deposited: 12 May 2021 16:07
Last Modified: 19 Jul 2022 10:21
URI: http://eprints.uni-mysore.ac.in/id/eprint/13875

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