Mahadevappa, D. S. and Jadhav, M. B. and Naidu, H. M. K. (1980) Kinetics and mechanism of the oxidation of dimethyl sulfoxide by chloramine-T in hydrochloric and medium. Reaction Kinetics and Catalysis Letters, 14 (1). pp. 15-20. ISSN 0133-1736
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Abstract
The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine-T (CAT) in HCl medium obeys the rate law - d log CAT/dt=kDMSO0.5H+. The active species in the oxidation is N-chloro-p-toluenesulfonamide. Chloride ion catalyzes the reaction. An order dependence of 1.7 on the gross concentration of HCl is obtained, indicating mixed order kinetics, with simultaneous catalysis by H+ and Cl- ions. © 1980 Akadémiai Kiadó.
| Item Type: | Article |
|---|---|
| Additional Information: | Publisher: Kluwer Academic Publishers |
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Dhruva Kumar |
| Date Deposited: | 12 May 2021 15:44 |
| Last Modified: | 12 May 2021 15:44 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/13867 |
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