Three 4-(4-fluoro­phen­yl)piperazin-1-ium salts containing organic anions: supra­molecular assembly in one, two and three dimensions

Harish Chinthal, Chayanna and Yathirajan, H. S. and Archana, S. D. and Foro, Sabine and Glidewell, Christopher (2020) Three 4-(4-fluoro­phen­yl)piperazin-1-ium salts containing organic anions: supra­molecular assembly in one, two and three dimensions. Acta Crystallographica Section E, 76 (6). pp. 841-847. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S2056989020006398

Abstract

Three salts containing the 4-(4-fluoro­phen­yl)piperazin-1-ium cation have been prepared and structurally characterized. In 4-(4-fluoro­phen­yl)piperazin-1-ium 2-hy­droxy-3,5-di­nitro­benzoate, C10H14FN2+·C7H3N2O7−, (I), the anion contains an intra­molecular O—H⋯O hydrogen bond, and it has a structure similar to that of the picrate ion. The cations and anions are linked into [001] chains of rings by a combination of two three-centre N—H⋯(O)2 hydrogen bonds. The anion in 4-(4-fluoro­phen­yl)piperazin-1-ium hydrogen oxalate, C10H14FN2+·C2HO4−, (II), is planar, and the cations and anions are linked into (100) sheets by multiple hydrogen bonds including two-centre N—H⋯O, three-centre N—H⋯(O)2, O—H⋯O, C—H⋯O and C—H⋯π(arene) types. In 4-(4-fluoro­phen­yl)piperazin-1-ium hydrogen (2R,3R)-tartrate monohydrate, C10H14FN2+·C4H5O6−·H2O, (III), the anion exhibits an approximate non-crystallographic twofold rotation symmetry with anti­periplanar carboxyl groups. A combination of eight hydrogen bonds, encompassing two- and three-centre N—H⋯O systems, O—H⋯O and C—H⋯π(arene) types, link the independent components into a three-dimensional framework. Comparisons are made with some related structures.

Item Type: Article
Uncontrolled Keywords: piperazines, piperazinium salts, crystal structure, molecular conformation, hydrogen bonding, supramolecular assembly
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 17 Jun 2020 09:36
Last Modified: 17 Jun 2020 09:36
URI: http://eprints.uni-mysore.ac.in/id/eprint/12101

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