Venkatachalapathy, R. and Veerabhadraswamy, M. and Rangaswamy (2001) Oxidation of para-methoxy benzaldehyde and salicylaldehyde by N-sodio-N-chlorotoluene sulphonamide (chloramine-T) in acid medium: A kinetic and mechanistic study. Asian Journal Of Chemistry, 13 (1). pp. 221-225.
Full text not available from this repository. (Request a copy)Abstract
The kinetics of oxidation of para-methoxy benzaldehyde and salicylaldehyde by chloramine-T (CAT) have been investigated in hydrochloric acid medium at 303 K. The rate shows first order dependence on CAT] and fractional order in aldehyde]. The rate increases with increase in HCl] and shows first order dependence on H+] and Cl-], variation of ionic strength, addition of reaction product (para-toluene sulphonamide) and change in dielectric constant of the medium had no significant effect on the reaction rate. Thermodynamic parameters are evaluated.
| Item Type: | Article |
|---|---|
| Divisions: | Department of > Chemistry |
| Depositing User: | Harisha R uom |
| Date Deposited: | 30 Jan 2021 10:31 |
| Last Modified: | 30 Jan 2021 10:31 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/10129 |
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