Mallya, M. Narendra and Nagendrappa, G. and Shashidhara Prasad, J. and Sridhar, M. A. and Lokanath, N. K. and Noor shahina Begum (2001) Addition of NOCl to cyclic vinylsilanes: an unexpected reversal of regiochemistry. Tetrahedron Letters, 42 (13). pp. 2565-2568. ISSN 0040-4039
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Official URL: https://doi.org/10.1016/S0040-4039(01)00190-3
Abstract
NOCl adds to cyclic vinylsilanes in a syn manner with NO+ bonding to the beta -carbon and Cl- to the alpha -carbon, which is a reversal of the regiochemistry expected from the beta -silicon effect. The adducts dimerize to a single diastereomer containing enantiomeric pairs and/or give secondary products on further reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | NOCl; vinylsilanes; nitrososilanes; silylated diazene dioxides |
| Subjects: | D Physical Science > Physics |
| Divisions: | Department of > Physics |
| Depositing User: | Harisha R uom |
| Date Deposited: | 15 Apr 2021 06:14 |
| Last Modified: | 29 Jun 2022 07:48 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/10115 |
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