Kaur, M. and Jasinski, J. P. and Kavitha, C. N. and Yathirajan, H. S. and Byrappa, K. (2014) 2-(4-nitrobenzylidene)amino-4,5,6,7-tetrahydro-1-benzothiophen-3-yl -(phenyl)methanone. Acta Crystallographica Section E: Crystallographic Communications, E70 (6). o738-o739. ISSN 2056-9890
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Abstract
In the title compound, C22H18N2O3S, disorder is found in the benzoyl group (A and B), as well as for four C atoms of the cyclohexene ring. Two orientations were modeled in a 0.583 (5):0.417 (5) ratio. The cyclohexene ring is in a distorted chair conformation. The dihedral angles between the mean plane of the thiophene ring and the 4-nitrobenzene and phenyl rings are 30.9 (8) and 64.8 (3) (A) and 62.4 (7)° (B). The mean planes of the 4-nitrobenzene and the phenyl rings are almost perpendicular to each other, with dihedral angles of 85.4 (1) (A) and 83.9 (8)° (B). An extensive array of weak C-H...O interactions consolidate molecules into a three-dimensional architecture, forming chains along [001] and [010] and layers parallel to (011).
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Arshiya Kousar Library Assistant |
| Date Deposited: | 25 Jun 2019 06:12 |
| Last Modified: | 25 Jun 2019 06:12 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/3710 |
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