Lomefloxacinium picrate

Jasinski, J. P. and Butcher, R. J. and Siddegowda, M. S. and Yathirajan, H. S. and Al-arique, Q. N. M. H. (2011) Lomefloxacinium picrate. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67 (2). O483-U1654. ISSN 1600-5368

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Official URL: doi:10.1107/S1600536811002534


In the cation of the title compound systematic name: (RS)-4-(3-carboxy-1-ethyl-6,8-difluoro-4-oxo-1,4-dihydroquinolin-7yl)-2- methylpiperazin-1-ium 2,4,6-trinitrophenolate], C17H20F2N3O3+center dot C6H2N3O7-, the piperazine ring adopts a slightly distorted chair conformation and contains a protonated N atom. An intramolecular O-H center dot center dot center dot O hydrogen bond occurs in the cation. The dihedral angles between the mean planes of the six-atom piperazine ring and the 10-atom fused ring system is 43.3 (5)degrees. The picrate anion interacts with the protonated N atom of an adjacent cation through a bifurcated N-H center dot center dot center dot(O, O) three-center hydrogen bond. Strong N-H center dot center dot center dot O hydrogen bonds in concert with weak pi-pi stacking interactions centroid-centroid distance = 3.6460 (14) angstrom] dominate the crystal packing, creating a two-dimensional network structure along 011].

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa venkatesh user
Date Deposited: 24 Jun 2019 10:22
Last Modified: 14 Mar 2020 10:36
URI: http://eprints.uni-mysore.ac.in/id/eprint/2565

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