The crystal structure of (E)-2-ethyl-N-(4-nitro­benzyl­idene)aniline: three-dimensional supra­molecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) inter­actions

Girisha, M. and Sagar, B. K. and Yathirajan, H. S. and Rathore, Ravindranath S. and Glidewell, Christopher (2018) The crystal structure of (E)-2-ethyl-N-(4-nitro­benzyl­idene)aniline: three-dimensional supra­molecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) inter­actions. Acta Crystallographica Section E, 74 (8). pp. 1071-1074. ISSN 1071-1074

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Official URL: https://doi.org/10.1107/S2056989018009544

Abstract

In the mol­ecule of the title compound, C15H14N2O2, the 2-ethyl­phenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H...O hydrogen bonds and nitro...π(arene) inter­actions links the mol­ecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.

Item Type: Article
Uncontrolled Keywords: Schiff bases, crystal structure, disorder, molecular conformation, hydrogen bonding, nitro...pi(arene) interactions, supramolecular assembly
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Manjula P Library Assistant
Date Deposited: 06 Nov 2019 08:08
Last Modified: 06 Nov 2019 08:08
URI: http://eprints.uni-mysore.ac.in/id/eprint/9844

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