Ethyl 4-(2,4-di­chloro­phen­yl)-6-(6-meth­­oxy-2-naphth­yl)-2-oxo­cyclo­hex-3-ene-1-carboxyl­ate

Harrison, William T. A. and Mayekar, A. N. and Yathirajan, H. S. and Narayana, B. and Sarojini, B. K. (2010) Ethyl 4-(2,4-di­chloro­phen­yl)-6-(6-meth­­oxy-2-naphth­yl)-2-oxo­cyclo­hex-3-ene-1-carboxyl­ate. Acta Crystallographica Section E, 66 (10). o2478. ISSN 2056-9890

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In the title compound, C26H22Cl2O4, the cyclo­hexenone ring adopts an approximate half-chair conformation, with two C atoms displaced by −0.485 (6) and 0.218 (6) Å from the plane of the other four ring atoms. The dihedral angles between its four almost coplanar [maximum deviation = 0.006 (2) Å] atoms and the benzene and naphthalene ring systems are 59.26 (13) and 79.94 (9)°, respectively. The dihedral angle between the aromatic rings systems is 77.14 (7)°. A short intra­molecular C—H⋯Cl contact generates an S(6) ring. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯Cl inter­actions to generate a three-dimensional network.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 02 Nov 2019 05:51
Last Modified: 02 Nov 2019 05:51

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