Kaur, Manpreet and Jasinski, Jerry P. and Kavitha, C. N. and Yathirajan, H. S. and Byrappa, K. (2014) [2-(Benzyl­­idene­amino)-4,5,6,7-tetra­hydro­benzo[b]thio­phen-3-yl](phen­yl)methanone. Acta Crystallographica Section E, 70 (5). o507-o508. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S1600536814006679


In the title compound, C22H19NOS, the cyclo­hexene ring of the tetra­hydro­benzo­thio­phenyl ring system adopts a slightly distorted half-chair conformation and is twisted slightly [7.5 (8)° for the major disorder component] from the mean plane of the thio­phene ring. The dihedral angles between the mean planes of the thio­phene ring and the phenyl rings are 65.7 (3) and 8.3 (4)°. The phenyl rings are twisted with respect to each other by 73.8 (7)°. Disorder was modeled for four C atoms of the cyclo­hexene ring over two sets of sites with an occupancy ratio of 0.659 (2):0.341 (2). In the crystal, a single weak C—H⋯O inter­action links the mol­ecules into [001] chains.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: MUL SWAPNA user
Date Deposited: 02 Nov 2019 05:09
Last Modified: 02 Nov 2019 05:09
URI: http://eprints.uni-mysore.ac.in/id/eprint/9736

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