Crystal structure and hirshfeld surface analysis of bis (2-(2-(1H-benzodimidazol-2-yl)hydrazono)propan-1-ol) nickel(II) chloride

Kamat, Vinayak and Karthik Kumara and Shaikh, Sabiha and Naveen, S. and Lokanath, N. K. and Revankar, Vidyanand (2018) Crystal structure and hirshfeld surface analysis of bis (2-(2-(1H-benzodimidazol-2-yl)hydrazono)propan-1-ol) nickel(II) chloride. Chemical Data Collections, 17-18. 251 - 262.

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The present work describes the crystal structure and Hirshfeld surface analysis of a transition metal coordination complex, bis (2-(2-(1H-benzodimidazol-2-yl)hydrazono)propan-1-ol) nickel(II) chloride.Recrystallization of the title complex from aqueous methanol has crystallized the complex in monoclinic crystal system with P21/c space group. The asymmetric unit of the complex has two monomeric distorted octahedral coordination entities, along with four chloride anions and seven water molecules as crystallization solvent. The ring puckering analysis, intramolecular hydrogen and halogen bonding interactions and the CH⋯π and π–π interactions of the complex are explored. Further, the Hirshfeld surface analysisis carried out to reveal the nature and contributions of individual intermolecular interactions and the importance of the CH⋯π and π–π interactions in the crystal packing.

Item Type: Article
Uncontrolled Keywords: Nickel complex, Crystal structure, Hydrazone lignad, Hirshfeld surface analysis
Subjects: D Physical Science > Physics
Divisions: Department of > Physics
Depositing User: Manjula P Library Assistant
Date Deposited: 24 Oct 2019 08:16
Last Modified: 24 Oct 2019 08:16

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