C—halogen⋯π dimer and C—H⋯π interactions in 1-(2-bromo-4,5-di­meth­­oxy­benzyl)-2-butyl-4-chloro-1H-imidazole-5-carbaldehyde and 2-butyl-4-chloro-1-(6-methyl-1,3-benzodioxol-5-ylmethyl)-1H-imidazole-5-carbaldehyde

Nagaraj, B. and Narasimhamurthy, T. and Yathirajan, H. S. and Nagaraja, P. and Narasegowda, R. S. and Rathore, Ravindranath S. (2005) C—halogen⋯π dimer and C—H⋯π interactions in 1-(2-bromo-4,5-di­meth­­oxy­benzyl)-2-butyl-4-chloro-1H-imidazole-5-carbaldehyde and 2-butyl-4-chloro-1-(6-methyl-1,3-benzodioxol-5-ylmethyl)-1H-imidazole-5-carbaldehyde. Acta Crystallographica Section C, 61 (3). o177-o180. ISSN 2053-2296

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Official URL: https://doi.org/10.1107/S0108270105001794

Abstract

The structures of the title compounds, C17H20BrClN2O3, (I), and C17H19ClN2O3, (II), are stabilized by intramolecular C—H⋯O and C—H⋯π interactions. The stability of the molecular packing in (I) and (II) arises from a diverse set of weak intermolecular C—H⋯O, C—H⋯π and C—halogen⋯π interactions. In the crystal structure of (I), mol­ecules aggregate in dimeric subunits via C—Br⋯π interactions. The dimers are interlinked by C—H⋯O hydrogen bonds. The halogens cluster together and form a channel along the b axis. In (II), the packing is mainly governed by intermolecular C—H⋯O and C—H⋯π interactions.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: MUL SWAPNA user
Date Deposited: 18 Oct 2019 07:15
Last Modified: 18 Oct 2019 07:15
URI: http://eprints.uni-mysore.ac.in/id/eprint/9284

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