1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­­idene)di­hydroxyl­amine

Samshuddin, S. and Butcher, Ray J. and Akkurt, Mehmet and Narayana, B. and Yathirajan, H. S. and Sarojini, B. K. (2011) 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­­idene)di­hydroxyl­amine. Acta Crystallographica Section E, 67 (8). o1954-o1955. ISSN 2056-9890

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Abstract

The title compound, C15H12F2N2O2, crystallizes with two mol­ecules (A and B) in the asymmetric unit. Both aromatic rings of both mol­ecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for mol­ecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for mol­ecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)° for mol­ecule A, and 70.2 (4) and 71.5 (2)° for mol­ecule B. In the crystal, both mol­ecules form inversion dimers with R22(6) ring motifs via pairs of inter­molecular O—H⋯N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C—H⋯π inter­actions help to consolidate the packing.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	C Swapna Library Assistant
Date Deposited:	18 Oct 2019 06:06
Last Modified:	04 Aug 2022 09:34
URI:	http://eprints.uni-mysore.ac.in/id/eprint/9273

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