Yathirajan, H. S. and Mahadevappa, D. S. (1982) Kinetics and mechanism of oxidation of allyl and crotyl alcohols by sodium N-chlorobenzenesulphonamide in hydrochloric acid medium. Collection of Czechoslovak Chemical Communications, 47 (7). pp. 1826-1837. ISSN 1212-6950
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Materials and Methods All solutions were prepared in triply distilled water. Allyl alcohol (E. Merck, corrected bp 97'I D C, liD 1-412) and crotyl alcohol (Fluka, bp 125DC, liD 1'424) were used without further purification. The purity of the compounds was checked by phthalation with phthalic anhydride in pyridine!. The requisite amount of alcohols was accurately weighed and dissolved in water to get an approximately 0'5M solution. Chloramine B was prepared by passing pure chlorine through benzenesulphonamidez dissolved in NaOH solution (4M) over a period of one hour at 70 e. The mass obtained was filtered, dried and crystallised from water. The purity of the compound was checked by estimating the amount of active chlorine present in the compound. An aqueous solution of CAB was prepared and standardised by the iodometric method. The ionic strength was kept constant at a high value using a concentrated
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | C Swapna Library Assistant |
| Date Deposited: | 17 Oct 2019 10:03 |
| Last Modified: | 17 Oct 2019 10:03 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/9256 |
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