Kinetics and mechanism of oxidation of allyl and crotyl alcohols by sodium N-chlorobenzenesulphonamide in hydrochloric acid medium

Yathirajan, H. S. and Mahadevappa, D. S. (1982) Kinetics and mechanism of oxidation of allyl and crotyl alcohols by sodium N-chlorobenzenesulphonamide in hydrochloric acid medium. Collection of Czechoslovak Chemical Communications, 47 (7). pp. 1826-1837. ISSN 1212-6950

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Official URL: https://doi.org/10.1135/cccc19821826

Abstract

Materials and Methods All solutions were prepared in triply distilled water. Allyl alcohol (E. Merck, corrected bp 97'I D C, liD 1-412) and crotyl alcohol (Fluka, bp 125DC, liD 1'424) were used without further purification. The purity of the compounds was checked by phthalation with phthalic anhydride in pyridine!. The requisite amount of alcohols was accurately weighed and dissolved in water to get an approximately 0'5M solution. Chloramine B was prepared by passing pure chlorine through benzenesulphonamidez dissolved in NaOH solution (4M) over a period of one hour at 70 e. The mass obtained was filtered, dried and crystallised from water. The purity of the compound was checked by estimating the amount of active chlorine present in the compound. An aqueous solution of CAB was prepared and standardised by the iodometric method. The ionic strength was kept constant at a high value using a concentrated

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 17 Oct 2019 10:03
Last Modified: 17 Oct 2019 10:03
URI: http://eprints.uni-mysore.ac.in/id/eprint/9256

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