2-(2-{Chlorophenyl})(hydroxy)methylphenol

Prakasha, G. and Jasinski, J. P. and Brown, J. S. and Yathirajan, H. S. and Ravishankara, D. K. (2013) 2-(2-{Chlorophenyl})(hydroxy)methylphenol. Acta Crystallographica Section E: Structure Reports Online, 69 (8). o1240. ISSN 1600-5368

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Official URL: http://doi.org/10.1107/S1600536813018667

Abstract

In the title compound, C13H11ClO2, the dihedral angle between the mean planes of the 2-chlorophenyl and phenol rings is 87.4 (9). The methyl hydroxy group lies nearly perpendicular to the plane of its attached benzene ring [O— C—C—C torsion angle = 84.3 (3)]. The two hydroxy groups lie on the same side of the molecule and are in a slightly twisted gauche conformation [O—C—C—O torsion angle = 77.1 (8)] to each other. In the crystal, O—HO hydrogen bonds between nearby methylhydroxy groups form dimers in alternating pairs aligned diagonally along the b axis. A view along the c axis reveals a hexameric aggregate mediated by a ring of six O—HO hydrogen bonds generating an R6 6 (12) motif loop.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Arshiya Kousar
Date Deposited: 22 Oct 2019 05:55
Last Modified: 22 Oct 2019 05:55
URI: http://eprints.uni-mysore.ac.in/id/eprint/9135

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