Kinetics and mechanism of the oxidation of dimethyl sulfoxide by chloramine-T in hydrochloric acid medium.

Mahadevappa, D. S. and Jadhav, M. B. and Naidu, H. M. K. (1980) Kinetics and mechanism of the oxidation of dimethyl sulfoxide by chloramine-T in hydrochloric acid medium. Reaction Kinetics and Catalysis Letters, 14 (1, Cop). pp. 15-20. ISSN 0304-4122

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Official URL: http://dx.doi.org/10.1007/BF02061257

Abstract

The kinetics of oxidn. of DMSO by chloramine-T in HCl indicates that the active species in the oxidn. is p-MeC6H4SO2NHCl. Cl- catalyzes the reaction. An order dependence of 1.7 on the gross concn. of HCl is obtained, indicating mixed order kinetics, with simultaneous catalysis by H+ and Cl- ions. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 1980/// [EPrints field already has value set] M3 - 10.1007/BF02061257 [Field not mapped to EPrints] JA - React. Kinet. Catal. Lett. [Field not mapped to EPrints]
Uncontrolled Keywords: kinetics oxidn DMSO chloramine T, mechanism oxidn DMSO chloramine T, chloride oxidn DMSO catalyst
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Dhruvakumar
Date Deposited: 15 May 2013 10:12
Last Modified: 15 May 2013 10:12
URI: http://eprints.uni-mysore.ac.in/id/eprint/9080

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