N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl) -2-phenylacetamide

Kaur, M. and Jasinski, J. P. and Anderson, B. J. and Yathirajan, H. S. and Narayana, B. (2013) N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl) -2-phenylacetamide. Acta Crystallographica Section E: Structure Reports Online, 69 (12). o1726-o1727. ISSN 1600-5368

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Official URL: http://doi.org/10.1107/S1600536813029590


The title compound, C19H19N3O2, crystallizes with two independent molecules (A and B) in the asymmetric unit. In molecule A, the pyrazole ring adopts a slightly disordered half-chair conformation while in B it is planar r.m.s. deviation = 0.0386 (15) à . The dihedral angle between the mean planes of the two phenyl rings is 56.2 (8) in A and 38.2 (3)° in B. The N-phenyl substituent on the pyrazole ring is twisted by 46.5 (2) in A and 58.6 (4)° in B while the extended phenyl ring is twisted by 82.2 (8) in A and 87.5 (9)° in B. The mean plane of the amide group forms an angle of 74.8 (3) in A and 67.7 (1)° in B with respect to the phenyl ring. In addition, the amide group is rotated by 51.4 (1) in A and 53.6 (2)° in B from the the mean plane of the pyrazole ring. In the crystal, the two molecules are linked via N-H�O hydrogen bonds, supported by weak C-H�O interactions, forming dimers enclosing an R 22(10) ring motif. The dimers are linked via C-H�O interactions, forming a three-dimensional structure.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Arshiya Kousar
Date Deposited: 11 Oct 2019 05:44
Last Modified: 11 Oct 2019 05:44
URI: http://eprints.uni-mysore.ac.in/id/eprint/8814

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