Reinvestigation of the crystal structure of N-(4-chloro-benzyl-idene)-2-hy-droxy-aniline: a three-dimensional structure containing O-H⋯N, O-H⋯O and C-H⋯π(arene) hydrogen bonds.

Girisha, M. and Yathirajan, H. S. and Rathore, Ravindranath S. and Glidewell, Christopher (2018) Reinvestigation of the crystal structure of N-(4-chloro-benzyl-idene)-2-hy-droxy-aniline: a three-dimensional structure containing O-H⋯N, O-H⋯O and C-H⋯π(arene) hydrogen bonds. Acta Crystallographica Section E, 74 (3). pp. 376-379. ISSN 1600-5368

Text (Full Text) Reinvestigation of the crystal structure.pdf - Published Version Download (671kB)

Abstract

The mol-ecule of the title compound, C13H10ClNO, (I), which contains an intra-molecular O-H⋯N hydrogen bond, is almost planar: the dihedral angle between the two aryl rings is only 3.31 (9)°. The mol-ecules of (I) are linked into sheets by two C-H⋯π(arene) hydrogen bonds and the sheets are linked into a three-dimensional structure by O-H⋯O hydrogen bonds. Comparisons are made with the structures of a number of related compounds.

Item Type:	Article
Uncontrolled Keywords:	crystal structure, Schiff bases, molecular conformation, hydrogen bonding, supramolecular assembly
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	LA manjunath user
Date Deposited:	27 Sep 2019 05:11
Last Modified:	15 Oct 2019 05:45
URI:	http://eprints.uni-mysore.ac.in/id/eprint/8571

Actions (login required)

View Item