Kinetics and mechanism of oxidation of 4-oxoacids by hexacyanoferrate(III) catalysed by Os(VIII)

Gnana Rani, D. F. and Maria Pushparaj, F. J. and Alphonse, I. and Rangappa, K. S. (2002) Kinetics and mechanism of oxidation of 4-oxoacids by hexacyanoferrate(III) catalysed by Os(VIII). Indian journal of chemistry section B organic chemistry including medicinal chemistry, 41 (10). pp. 2153-2159. ISSN 0975-0983

[img] Text (Full Text)
Kinetics a nd mechanism of oxidJtio n of 4-oxoacids.pdf - Published Version
Restricted to Registered users only

Download (1MB) | Request a copy
Official URL: http://nopr.niscair.res.in/handle/123456789/22071

Abstract

Kinetics of Os(VIII) catalysed oxidation of substituted and unsubstituted 4-oxoacids by alkaline hexacyanoferrate(III) in sodium carbonate-bicarbonate buffer have been studied. The reaction is zero order in oxidant, first order with respect to Os(VIII), first order at higher concentrations and zero order at lower concentrations with respect to both substrate and alkali. The activation parameters have been computed.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: manjula User
Date Deposited: 26 Sep 2019 07:31
Last Modified: 26 Sep 2019 07:31
URI: http://eprints.uni-mysore.ac.in/id/eprint/8546

Actions (login required)

View Item View Item