Synthesis, Growth, and Characterization of Sodium Coordinated Glycine-Nlo Material

Jayalakshmi, K. and Sridhar, M. A. and Shashidhara Prasad, J. and Bhat, M. Narayan and Dharmaprakash, S. M. (2003) Synthesis, Growth, and Characterization of Sodium Coordinated Glycine-Nlo Material. Molecular Crystals and Liquid Crystals, 393 (1). pp. 95-103. ISSN 1563-5287

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A new complex of the amino acid glycine has been synthesized by coordination with sodium nitrate. The title complex, Na(CH2NH2COOH)(2)NO3, crystallizes in the monoclinic space group, Cc , with parameters a = 14.331(2) Angstrom, b = 5.262(2) Angstrom, c = 9.119(2) Angstrom, beta = 119.08(1)degrees, V = 600.8(2) Angstrom(3) , Z = 4, F.W. = 159.06, D-c = 1.758 Mg.m(-3), F-000 = 324, lambda(MoKalpha) = 0.71069 Angstrom, mu = 0.228 mm(-1), R1 = 0.0481. The compound exhibits some novel structural features. The optical second harmonic generation conversion efficiency was determined using Kurtz powder technique. It was found to be twice that of Potassium Diortho Phosphate (KDP).

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: LA manjunath user
Date Deposited: 24 Sep 2019 06:04
Last Modified: 07 Jul 2022 10:16

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