Synthesis and crystal structure of 1-methyl-3-(4-nitrophenyl)-1,2,3 triazolium perchlorate

Doreswamy, B. H. and Mahendra, M. and Sridhar, M. A. and Shashidhara Prasad, J. and Mantelingu, K. and Basappa, K. and Rangappa, K. S. (2003) Synthesis and crystal structure of 1-methyl-3-(4-nitrophenyl)-1,2,3 triazolium perchlorate. Molecular Crystals and Liquid Crystals, 403 (1). pp. 67-75. ISSN 1563-5287

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Abstract

The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-methyl-3-(4-nitrophenyl)-1,2,3 triazolium perchlorate (6). The title compound (C-9 H-11 Cl N-4 O-6) was isolated and structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P2(1)/c with cell parameters a = 9.704(1) Angstrom, b =12.580(2) Angstrom, c = 13.684(8) Angstrom, Z = 4. The molecules appear to be stacked.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Divisions:	Department of > Chemistry
Depositing User:	LA manjunath user
Date Deposited:	24 Sep 2019 05:52
Last Modified:	07 Jul 2022 10:16
URI:	http://eprints.uni-mysore.ac.in/id/eprint/8430

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