Kinetics of oxidation of indole in high indole concentration range by bromamine-B in alkaline medium catalysed by Os(VIII)

Demappa, T. and Ananda, S. (2000) Kinetics of oxidation of indole in high indole concentration range by bromamine-B in alkaline medium catalysed by Os(VIII). Asian Journal of Chemistry, 12 (4). pp. 1282-1290. ISSN 0970-7077

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Abstract

The kinetics of oxidation of indole (In) in high indole concentration range by sodium N-bromobenzene sulphonamide (BAB) in alkaline medium in presence of OsO4 catalyst have been investigated at 30 degreesC The reaction rate shows a first order dependence of rate on BAB](0) and Indole], and inverse first order dependence of rate on OH-] and first order on OsO4]. Addition of halide ions and variation of ionic strength and dielectric constant of the medium do not have any signficant effect on the reaction rate. Thermodynamic parameters have been evaluated.

Item Type: Article
Subjects: M Polymer Science > Polymer Science
Divisions: PG Centre Mandya > Polymer Science
Depositing User: Shrirekha N
Date Deposited: 20 Sep 2019 10:03
Last Modified: 20 Sep 2019 10:03
URI: http://eprints.uni-mysore.ac.in/id/eprint/8318

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