Mohana, K. N. and Prasad, N. (2007) Ruthenium(III)-catalyzed oxidation of 2-phenylethylamine with sodium N-chlorobenzenesulphonamide in hydrochloric acid solution: A kinetic and mechanistic study. Journal of Molecular Catalysis A: Chemical, 266 (1). 267 - 273. ISSN 1381-1169
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The kinetics of ruthenium(III)-catalyzed oxidation of 2-phenylethylamine (PEA) with sodium N-chlorobenzenesulphonamide or chloramine-B (CAB) in hydrochloric acid solution has been studied at 313K. The reaction rate shows first-order dependence each on CAB, H+ and Ru(III)Cl3 and fractional order on PEA and Cl−. Variation of ionic strength and addition of the reduction product of CAB has no significant effect on the rate. There is a negative effect of dielectric constant of the solvent. The stoichiometry of the reaction was found to be 1:1 and the oxidation product of 2-phenylethylamine was identified as phenyl acetaldehyde. The reaction was studied at different temperatures and the activation parameters have been evaluated from the Arrhenius plot. The reaction constants involved in the mechanisms were computed. RN+H2Cl has been postulated as the reactive oxidizing species. Mechanisms consistent with the observed kinetic data have been proposed and discussed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 2-Phenylethylamine, Chloramine-B, Ru(III)chloride catalysis, Oxidation kinetics |
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | C Swapna Library Assistant |
| Date Deposited: | 17 Sep 2019 06:36 |
| Last Modified: | 17 Sep 2019 06:36 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/8207 |
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