Synthesis, characterization and crystal structure studies of 1-(4-Chloro-benzenesulfonyl)- piperidin-4-yl-diphenyl-methanol

Benaka Prasad, S. B. and Naveen, S. and Ananda Kumar, C. S. and Sunil Kumar, Y. C. and Sridhar, M. A. and Shashidhara Prasad, J. and Rangappa, K. S. (2007) Synthesis, characterization and crystal structure studies of 1-(4-Chloro-benzenesulfonyl)- piperidin-4-yl-diphenyl-methanol. Polish Journal of Chemistry, 81 (5-6). pp. 1191-1199. ISSN 0137-5083

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1-(4-Chloro-benzenesulfonyl)-piperidin-4-yl-diphenyl-methanol was synthesized by the condensation of [piperidin-4-yl]-diphenyl-methanol with p-chlorobenzene sulfonylchloride in methylene dichloride as solvent and triethylamine as the base. The compound obtained was characterized by spectroscopic techniques and confirmed by X-ray crystallographic studies. The crystallographic data analysis reveals that the title compound crystallizes in the monoclinic space group P2(1)/c with cell parameters a = 10.214(9) angstrom, b = 11.371(5) angstrom, c = 20.939(16) angstrom, beta = 115.399(2)degrees, V = 2197(3) angstrom(3) for Z = 4. The structure has been solved by direct methods and refined to R-1 = 0.0560 for 3658 observed reflections with I > 2 sigma(I). The piperidine ring is in a chair conformation. The geometry around the S atom is distorted from regular tetrahedron.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: MUL SWAPNA user
Date Deposited: 17 Sep 2019 06:19
Last Modified: 12 Mar 2020 06:29

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