A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives

Gaonkar, S. L. and Lokanatha Rai, K. M. (2005) A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives. Journal of Heterocyclic Chemistry, 42 (5). pp. 877-881. ISSN 1943-5193

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Official URL: https://doi.org/10.1002/jhet.5570420520

Abstract

Abstract Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with tri-ethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermol-ecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: manjula User
Date Deposited: 16 Sep 2019 11:16
Last Modified: 16 Sep 2019 11:16
URI: http://eprints.uni-mysore.ac.in/id/eprint/8186

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