Rapid cleavage of azo compounds to amine/s using Raney nickel and ammonium formate or formic acid

Gowda, D. C. and Gowda, S. and Abiraj, K. (2003) Rapid cleavage of azo compounds to amine/s using Raney nickel and ammonium formate or formic acid. Indian Journal of Chemistry Section B-Organic Chemistry Including Medicinal Chemistry, 42 (7). pp. 1774-1776. ISSN 0975-0983

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Abstract

Azo compounds, both symmetrical and unsymmetrical are cleaved to amine/s by using Raney nickel and ammonium formate or formic acid in methanol at room temperature. The reductive cleavage is very fast, clean, cost effective and high yielding as compared to earlier methods and many other functionality such as -OH, -CH3 -OCH3, -COOH, -COCH3 and halogen remained unaffected.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: lpa manjunath user
Date Deposited: 07 Sep 2019 11:22
Last Modified: 07 Sep 2019 11:22
URI: http://eprints.uni-mysore.ac.in/id/eprint/7798

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