Synthesis and crystal structure of 1-ethyl-3-(phenyl)-1,2,3-triazolium percholorate

Doreswamy, B. H. and Mahendra, M. and Anandalwar, Sridhar M. and Shashidhara Prasad, J. and Mantelingu, K. and Basappa and Rangappa, K. S. (2003) Synthesis and crystal structure of 1-ethyl-3-(phenyl)-1,2,3-triazolium percholorate. Central European Journal of Chemistry, 1 (4). pp. 477-490. ISSN 1644-3624

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The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-ethyl-3-(phenyl)-1,2,3-triazolium perchlorate (6+). The title compound C10H14Cl N3O4 was isolated and structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P21/c with cell parameters a=6.697(4) Å, b=9.724(9) Å, c=19.844(2) Å and Z=4. The final residual factor is R1=0.0471 for 1545 reflections with I>2σ(I). The structure exhibits intermolecular hydrogen bonds.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: LA manjunath user
Date Deposited: 07 Sep 2019 11:02
Last Modified: 11 Dec 2019 09:45

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