Butcher, Ray J. and Jasinski, Jerry P. and Mayekar, Anil N. and Yathirajan, H. S. and Narayana, B. (2007) 2-{5-Chloro-2-[(4-meth­oxy­benzyl)­amino]phen­yl}-4-cyclo­propyl-1,1,1-tri­fluoro­but-3-yn-2-ol. Acta Crystallographica Section E, 63 (9). o3703-o3704. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S160053680703749X


In the title mol­ecule, C21H19ClF3NO2, the 5-chloro­phenyl and 4-methoxy­benzyl groups are twisted slightly with respect to the amine group [dihedral angles = −8.4 (2) and 13.6 (2)°] and with respect to each other [6.2 (7)°], forming a nearly planar arrangement. The crystal packing is stabilized by intra­molecular N—H⋯O hydrogen bonding between the amine H atom and the hydroxyl O atom. In addition, inter­molecular hydrogen bonding between the same amine H atom and an F atom, N—H⋯F, and between the meth­oxy O atom and the hydroxyl H atom, O—H⋯O, adds to this stability.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 07 Sep 2019 10:20
Last Modified: 07 Sep 2019 10:20
URI: http://eprints.uni-mysore.ac.in/id/eprint/7776

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