Crystal structure of bis(2-butyl-4-chloro-imidazole)5-iminoethane

Yathirajan, H. S. and Raju, C. R. and Lokanatha Rai, K. M. and Jailakshmi, K. and Nagaraja, P. and Palani, K. and Ponnuswamy, M. N. and Nethaji, M. (2005) Crystal structure of bis(2-butyl-4-chloro-imidazole)5-iminoethane. Journal of Chemical Crystallography, 35 (3). pp. 211-215. ISSN 1572-8854

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Official URL: https://doi.org/10.1007/s10870-005-2959-0

Abstract

The title compound (C18H26N6Cl2) crystallizes in monoclinic space group P21/c with a = 14.867(4) Å}, b = 7.758(2) Å}, c = 9.671(3) Å}, β = 108.78(1)∘, V = 1056.0(5) Å}3, Z = 2, D cal = 1.250 Mg/m3 at T = 293 K. The structure was solved by direct methods and refined by full-matrix least-squares procedures to final R = 0.0650 and wR = 0.1719 using 2493 reflections. The imidazole ring is planar and the n-butyl chain adopts an extended conformation. The molecules in the crystal are stabilized by N–H ⋅s N type of intermolecular hydrogen bondings in addition to van der Waals forces.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: manjula User
Date Deposited: 07 Sep 2019 06:33
Last Modified: 07 Sep 2019 06:33
URI: http://eprints.uni-mysore.ac.in/id/eprint/7742

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