Palladium-catalyzed simple and efficient hydrogenative cleavage of azo compounds using recyclable polymer-supported formate

Abiraj, K. and Srinivasa, G. R. and Channe Gowda, D. (2005) Palladium-catalyzed simple and efficient hydrogenative cleavage of azo compounds using recyclable polymer-supported formate. Canadian Journal of Chemistry, 83 (5). pp. 517-520. ISSN 480-3291

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Official URL: https://doi.org/10.1139/v05-071

Abstract

Palladium-catalyzed room temperature transfer hydrogenation of azo compounds using recyclable polymer-supported formate as the hydrogen donor produces corresponding amine(s) in excellent yields (88%�98%). This method was found to be highly facile with selectivity over a number of other functional groups such as halogen, alkene, nitrile, carbonyl, amide, methoxy, and hydroxyl.Key words: azo compounds, catalytic transfer hydrogenation, polymer-supported formate, 10% Pd-C, amines.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: manjula User
Date Deposited: 05 Sep 2019 11:14
Last Modified: 02 Nov 2019 10:32
URI: http://eprints.uni-mysore.ac.in/id/eprint/7668

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