Do C-H⋅sO and C-H⋅sπ inter-actions help to stabilize a non-centrosymmetric structure for racemic 2,3-dibromo-1,3-diphenyl-propan-1-one?

Harrison, William T. A. and Yathirajan, H. S. and Sarojini, B. K. and Narayana, B. and Anilkumar, H. G. (2005) Do C-H⋅sO and C-H⋅sπ inter-actions help to stabilize a non-centrosymmetric structure for racemic 2,3-dibromo-1,3-diphenyl-propan-1-one? Acta Crystallographica Section C: Structural Chemistry, 61 (12). o728-o730. ISSN 2053-2296

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Official URL: https://doi.org/10.1107/S0108270105036942

Abstract

The racemic title compound, C\sb 15H\sb 12Br\sb 2O, crystallizes in a non-centrosymmetric structure and displays a significant non-linear optical response to red light. The crystal packing is influenced by C—-H⋅sO and C—-H⋅sπ inter\-actions. One of the former bonds has a short H⋅sO separation of 2.27Å.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Manjula P Library Assistant
Date Deposited: 04 Sep 2019 05:59
Last Modified: 04 Sep 2019 05:59
URI: http://eprints.uni-mysore.ac.in/id/eprint/7507

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