N-[2-(5-Bromo-2-morpholin-4-ylpyrim­idin-4-ylsulfan­yl)-4-meth­­oxy­phen­yl]-2,4,6-tri­methyl­benzene­sulfonamide

Mohan Kumar and Mallesha, L. and Sridhar, M. A. and Kamini Kapoor and Gupta, Vivek K. and Kant, Rajni (2012) N-[2-(5-Bromo-2-morpholin-4-ylpyrim­idin-4-ylsulfan­yl)-4-meth­­oxy­phen­yl]-2,4,6-tri­methyl­benzene­sulfonamide. Acta Crystallographica Section E, 68 (11). o3061. ISSN 2056-9890

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Abstract

In the title compound, C24H27BrN4O4S2, the mol­ecule is twisted at the sulfonyl S atom with a C—S(O2)—N(H)—C torsion angle of 62.6 (3)°. The benzene rings bridged by the sulfonamide group are tilted to each other by a dihedral angle of 60.6 (1)°. The dihedral angle between the sulfur-bridged pyrimidine and benzene rings is 62.7 (1)°. The morpholine ring adopts a chair conformation. The mol­ecular conformation is stabilized by a weak intra­molecular π–π stacking inter­action between the pyrimidine and the 2,4,6-trimethyl­benzene rings [centroid–centroid distance = 3.793 (2) Å]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a chain along the b axis.

Item Type:	Article
Subjects:	D Physical Science > Physics
Divisions:	Department of > Physics
Depositing User:	C Swapna Library Assistant
Date Deposited:	27 Aug 2019 09:54
Last Modified:	27 Aug 2019 09:54
URI:	http://eprints.uni-mysore.ac.in/id/eprint/7135

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