Synthesis and crystal structure of 1-(2-nitro-benzenesulfonyl)-piperidin-4-yl-diphenyl-methanol

Benaka Prasad, S. B. and Naveen, S. and Ananda Kumar, C. S. and Vinaya, K. and Linge Gowda, N. S. and Sridhar, M. A. and Shashidhara Prasad, J. and Rangappa, K. S. (2008) Synthesis and crystal structure of 1-(2-nitro-benzenesulfonyl)-piperidin-4-yl-diphenyl-methanol. Molecular Crystals and Liquid Crystals, 482 (1). pp. 145-154. ISSN 1563-5287

Text (Full Text) Synthesis and Crystal Structure of 1-(2-Nitro-.pdf - Published Version Restricted to Registered users only Download (576kB) | Request a copy

Abstract

The title compound 1-(2-nitro-benzenesulfonyl)-piperidin-4-yl-diphenyl-methanol was synthesized by the condensation of piperidin-4-yl-diphenyl-methanol with 2-nitro benzene sulfonylchloride in methylene dichloride as solvent and triethylamine as the base. The product obtained was characterized by spectroscopic techniques and the structure was investigated by X-ray crystallography. The compound crystallizes in the monoclinic crystal class in the space group Pc with cell parameters a = 9.2360(4) Å, b = 10.7750(8) Å, c = 13.4110(8) Å, β = 124.162(4)°, V = 1104.35(12)Å3 for Z = 2. The structure reveals that the piperidine ring is in a chair conformation. There is a large discrepancy around the bond angles of the piperidine N atom. The geometry around the S atom is distorted tetrahedron.

Item Type:	Article
Subjects:	C Chemical Science > Chemistry
Depositing User:	Manjula P Library Assistant
Date Deposited:	27 Aug 2019 06:00
Last Modified:	27 Aug 2019 06:00
URI:	http://eprints.uni-mysore.ac.in/id/eprint/7106

Actions (login required)

View Item