(6Z)-3,5-Bis(4-fluoro­phen­yl)-6-(1-hy­dr­oxy­ethyl­­idene)cyclo­hex-2-en-1-one

Jasinski, Jerry P. and Golen, James A. and Samshuddin, S. and Narayana, B. and Yathirajan, H. S. (2012) (6Z)-3,5-Bis(4-fluoro­phen­yl)-6-(1-hy­dr­oxy­ethyl­­idene)cyclo­hex-2-en-1-one. Acta Crystallographica Section E, 68 (3). o638-o639. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S1600536812003078

Abstract

In the title compound, C20H16F2O2, the cyclo­hex-2-en-1-one ring adopts a distorted envelope conformation and the dihedral angles between its six-atom mean plane and the fluorophenyl rings are 38.9(8) and 82.3(1)°. The two fluoro­phenyl rings are oriented at an angle of 77.3 (3)°. The long hy­droxy O—H bond length of 1.22 (3) and the H⋯O distance of 1.28 (3) Å, together with a longer than expected C=O bond length [1.290 (2) Å] in the hy­droxy(en-1-one) group, indicate sharing of the H atom as O⋯H⋯O between the two O atoms and the influence of electron delocalization. Weak C—H⋯O inter­molecular inter­actions form an infinite two-dimensional network in (011).

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: MUL SWAPNA user
Date Deposited: 26 Aug 2019 06:27
Last Modified: 26 Aug 2019 06:27
URI: http://eprints.uni-mysore.ac.in/id/eprint/7027

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