Structural conformation of a novel 1-benzhydrylpiperazine derivative: 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine

Naveen, S. and Ananda Kumar, C. S. and Benaka Prasad, S. B. and Vinaya, K. and Sridhar, M. A. and Shashidhara Prasad, J. and Rangappa, K. S. (2009) Structural conformation of a novel 1-benzhydrylpiperazine derivative: 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine. Journal of Chemical Crystallography, 39 (6). pp. 395-398. ISSN 1572-8854

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Official URL: http://doi.org/10.1007/s10870-008-9490-z

Abstract

The title compound 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine was synthesized and the structure was investigated by X-ray crystallography. The title compound, C24H26N2O2S crystallizes in the monoclinic crystal class in the space group P2(1)/c with cell parameters a = 13.5800(10) angstrom, b = 8.9630(7) angstrom, c = 18.9040(10) angstrom, beta = 106.851(3)degrees, Z = 4 and V = 2202.1(3) angstrom(3). The structure has been solved by direct methods and refined to R-1 = 0.0468 for 3174 observed reflections I > 2 sigma(I). The structure reveals that the piperazine ring is in a chair conformation. The geometry around the S atom is a distorted tetrahedron.

Item Type: Article
Uncontrolled Keywords: Benzhydrylpiperazine; Sulfonyl chloride; Crystal structure; Tetrahedral configuration
Subjects: C Chemical Science > Chemistry
D Physical Science > Physics
Divisions: Department of > Chemistry
Department of > Physics
Depositing User: Users 19 not found.
Date Deposited: 26 Aug 2019 05:50
Last Modified: 26 Aug 2019 05:50
URI: http://eprints.uni-mysore.ac.in/id/eprint/7006

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